1946 Nobel Prize in Physics
Reason for Award
for the invention of an apparatus to produce extremely high pressures, and for the discoveries he made therewith in the field of high pressure physics
Laureates
United States of America
Explanation
When you squeeze a balloon, the air inside tries to get smaller; that squeezing force is called pressure. Percy Bridgman invented a very strong metal cylinder and piston that could create pressures as huge as deep inside the Earth. Using it he squeezed ice, metals and rubber and saw their shape, hardness or color change. For example, ice turned into a strange new kind of solid and lead became harder than usual. Those findings led to technologies for making artificial gemstones and searching for new materials. They help us understand how everyday things change when they are put under extreme conditions.
Related Keywords
High-pressure physics
High-pressure physics explores how the structure and properties of matter change when subjected to extremely large pressures. By using pressure as a variable together with temperature and composition, researchers observe new crystal phases, metallization, superconductivity and other exotic phenomena. It provides the only experimental way to simulate the conditions inside Earth and other planets, linking the field closely to geoscience. Industrial applications range from super-hard tools and artificial gemstones to perovskite-type oxide development. Bridgman’s apparatus and datasets are regarded as the starting point that systematized this discipline.
Bridgman apparatus
The Bridgman apparatus is built around a piston-cylinder design that applies a quasi-hydrostatic pressure to the sample. Its hallmark is a self-sealing gasket and cell material that tighten as pressure rises. In the early 20th century it was the only laboratory device capable of maintaining pressures above 100 kbar for extended periods. Heating coils were integrated into the cell, enabling simultaneous temperature and pressure control and thus detailed phase-diagram studies. It served as the prototype for today’s multi-anvil and toroidal presses.
Phase transition
A phase transition is the change of a substance from one state or crystal structure to another, such as solid to liquid or one solid modification to another. Pressure strongly alters the temperature and mechanism of these transitions; under high pressure, phases that never exist at ordinary conditions can appear. Bridgman determined transition points of ice and metals from abrupt changes in volume and resistivity. Understanding phase transitions provides clues to tailoring the strength and electrical properties of materials. The concept is also crucial for mineralogy of Earth’s interior and the design of advanced functional materials.
Pressure unit
Units used to express pressure include pascal (Pa), bar, atmosphere (atm) and gigapascal (GPa). One atmosphere, the air pressure at sea level, equals about 1.013×10^5 Pa. The 40 GPa reached in Bridgman’s experiments corresponds to roughly 400,000 atm, recreating conditions hundreds of kilometres deep inside Earth. Accurate unit conversion is essential for comparing data and calibrating equipment. In modern high-pressure work the GPa is commonplace, and diamond-anvil cells can now reach several hundred GPa.
Compressibility
Compressibility quantifies how much a material’s volume decreases when pressure is applied; it is the reciprocal of the bulk modulus. A larger value means the substance is softer and easier to squeeze. From precise volume measurements Bridgman determined compressibilities for many metals and crystals, helping to establish equations of state. Such data are fundamental for calculating models of Earth’s interior in seismology and for designing materials that must operate at high pressure. Research on non-linear compressibility remains vital for discovering ultra-hard substances and superconductors.
Ice VII
Ice VII is a high-pressure cubic phase of water that forms at pressures above about 2 GPa even at room temperature. Its molecular arrangement is completely different from ordinary Ice I and is thought to exist deep inside Earth and water-rich planets. Bridgman produced it experimentally for the first time and reported its formation pressure and volume change. Ice VII has since been detected in diamond inclusions and shock-impact craters. Studying this phase greatly influences models of planetary water cycles and possible habitats for life.
Metallization
Metallization is the phenomenon in which an insulator or semiconductor becomes electrically conducting like a metal when high pressure alters its electronic band structure. Pressure narrows the band gap until it finally closes. Bridgman observed room-temperature metallization in materials such as bismuth and sulfur, showing that electronic properties can be reversibly tuned by pressure. This insight foreshadowed research into high-temperature superconductors and metallic hydrogen. Pressure-induced metallization remains a key concept for creating high-energy-density materials.
Diamond anvil cell
The diamond anvil cell (DAC) squeezes a sample between the tips of two diamonds and can now reach several hundred gigapascals. Because diamonds are transparent, optical spectroscopy and X-ray diffraction can be performed directly through them, a major advantage. The DAC miniaturizes and extends the pressure principle of Bridgman’s apparatus and was developed in the 1960s. Today it is the only laboratory tool that can reproduce pressures found at planetary cores. Applications range from high-pressure synthesis and biological molecule studies to laser-heating experiments.
Bridgman seal
The Bridgman seal inserts soft metal or PTFE between the piston and cylinder gap; as pressure rises the material flows and closes the gap, creating a self-sealing structure. This allowed high-pressure conditions to be maintained for hours to days. Choosing the right seal material and temperature profile is critical to prevent leaks and gasket failure. Many modern hydrostatic presses still use improved versions of the Bridgman seal. It remains a key engineering element that underpins apparatus performance and experimental reproducibility.
Equation of state
An equation of state (EoS) is a mathematical expression relating the pressure, volume and temperature of a substance, ranging from the ideal-gas law to Murnaghan and Eulerian models. High-pressure EoS data are essential inputs for modeling planetary density profiles and designing materials. Bridgman’s precise volume measurements provided some of the earliest systematic experimental EoS data at high pressures. Later scientists such as Birch extended the theory, and today first-principles calculations complement experiments to improve accuracy. EoS research finds use in materials science, geophysics and nuclear-fusion energy studies.